Theoretical study of finite temperature spectroscopy in van der Waals clusters. II Time-dependent absorption spectra

Using approximate partition functions and a master equation approach, we investigate the statistical relaxation toward equilibrium in selected CaAr$_n$ clusters. The Gaussian theory of absorption (previous article) is employed to calculate the average photoabsorption intensity associated with the 4s^2-> 4s^14p^1 transition of calcium as a function of time during relaxation. In CaAr_6 and CaAr_10 simple relaxation is observed with a single time scale. CaAr_13 exhibits much slower dynamics and the relaxation occurs over two distinct time scales. CaAr_37 shows much slower relaxation with multiple transients, reminiscent of glassy behavior due to competition between different low-energy structures. We interpret these results in terms of the underlying potential energy surfaces for these clusters.Comment: 10 pages, 9 figure

Embeddings of Sz(32) in E_8(5)

We show that the Suzuki group Sz(32) is a subgroup of E_8(5), and so is its automorphism group. Both are unique up to conjugacy in E_8(F) for any field F of characteristic 5, and the automorphism group Sz(32):5 is maximal in E_8(5)

A Poset Connected to Artin Monoids of Simply Laced Type

Let W be a Weyl group whose type is a simply laced Dynkin diagram. On several W-orbits of sets of mutually commuting reflections, a poset is described which plays a role in linear representatons of the corresponding Artin group A. The poset generalizes many properties of the usual order on positive roots of W given by height. In this paper, a linear representation of the positive monoid of A is defined by use of the poset

BMW algebras of simply laced type

It is known that the recently discovered representations of the Artin groups of type A_n, the braid groups, can be constructed via BMW algebras. We introduce similar algebras of type D_n and E_n which also lead to the newly found faithful representations of the Artin groups of the corresponding types. We establish finite dimensionality of these algebras. Moreover, they have ideals I_1 and I_2 with I_2 contained in I_1 such that the quotient with respect to I_1 is the Hecke algebra and I_1/I_2 is a module for the corresponding Artin group generalizing the Lawrence-Krammer representation. Finally we give conjectures on the structure, the dimension and parabolic subalgebras of the BMW algebra, as well as on a generalization of deformations to Brauer algebras for simply laced spherical type other than A_n.Comment: 39 page

Dutch listeners' use of suprasegmental cues to English stress

Dutch listeners outperform native listeners in identifying syllable stress in English. This is because lexical stress is more useful in recognition of spoken words of Dutch than of English, so that Dutch listeners pay greater attention to stress in general. We examined Dutch listeners’ use of the acoustic correlates of English stress. Primary- and secondary-stressed syllables differ significantly on acoustic measures, and some differences, in F0 especially, correlate with data of earlier listening experiments. The correlations found in the Dutch responses were not paralleled in data from native listeners. Thus the acoustic cues which distinguish English primary versus secondary stress are better exploited by Dutch than by native listeners

Structural trends in clusters of quadrupolar spheres

The influence of quadrupolar interactions on the structure of small clusters is investigated by adding a point quadrupole of variable strength to the Lennard-Jones potential. Competition arises between sheet-like arrangements of the particles, favoured by the quadrupoles, and compact structures, favoured by the isotropic Lennard-Jones attraction. Putative global potential energy minima are obtained for clusters of up to 25 particles using the basin-hopping algorithm. A number of structural motifs and growth sequences emerge, including star-like structures, tubes, shells and sheets. The results are discussed in the context of colloidal self-assembly.Comment: 8 pages, 6 figure

Saddle Points and Dynamics of Lennard-Jones Clusters, Solids and Supercooled Liquids

The properties of higher-index saddle points have been invoked in recent theories of the dynamics of supercooled liquids. Here we examine in detail a mapping of configurations to saddle points using minimization of $|\nabla E|^2$, which has been used in previous work to support these theories. The examples we consider are a two-dimensional model energy surface and binary Lennard-Jones liquids and solids. A shortcoming of the mapping is its failure to divide the potential energy surface into basins of attraction surrounding saddle points, because there are many minima of $|\nabla E|^2$ that do not correspond to stationary points of the potential energy. In fact, most liquid configurations are mapped to such points for the system we consider. We therefore develop an alternative route to investigate higher-index saddle points and obtain near complete distributions of saddles for small Lennard-Jones clusters. The distribution of the number of stationary points as a function of the index is found to be Gaussian, and the average energy increases linearly with saddle point index in agreement with previous results for bulk systems.Comment: 14 pages, 7 figure